123707-79-9Relevant articles and documents
Organotellurium chemistry: Remarkably facile preparation of benzo-1,3-tellurazoles
McMullen, Nathan C.,Fronczek, Frank R.,Junk, Thomas
, p. 120 - 124 (2013/04/10)
Benzo-1,3-tellurazoles carrying alkyl or aryl substituents in position 2 were prepared in a facile two-step sequence, starting with readily available 2-haloanilines. This approach relies on the preparation of bis(2-aminophenyl) ditellurides by nucleophilic halide displacement from 2-haloanilines with sodium telluride in N-methylpyrrolidone. Subsequent reductive cyclization with carboxylic acid halides or carboxylic anhydrides furnished benzo-1,3- tellurazoles in good yields.