123715-72-0Relevant academic research and scientific papers
SOLVOLYTIC REARRANGEMENTS IN 4β,5-CYCLOPROPANO-5β-ANDROSTANE-3β,17β,19-TRIOL 3-ACETATE 17-BENZOATE 19-p-TOLUENESULFONATE
Fajkos, Jan,Joska, Jiri
, p. 751 - 759 (2007/10/02)
The title tosylate V was prepared from the tosylate III by Simmons-Smith methylenation.Its acetolysis afforded three products with modified steroid skeletons: The diene VIII, the olefin XI, and the pentacyclic diacetate XIII.The 3-oxo derivatives XIV, XVI
