123725-24-6Relevant academic research and scientific papers
Acylsilenes (3-Oxo-1-sila-1-propenes) from Acyl(disilanyl)carbenes
Schneider, Klaus,Daucher, Birgit,Fronda, Antonio,Maas, Gerhard
, p. 589 - 594 (2007/10/02)
UV photolysis of diazo(disilanyl)methyl ketones 2 in benzene generates acyl(disilanyl)carbenes 3, which rearrange to 3-oxo-1-sila-1-propenes 4.The latter compounds are reactive intermediates which either cyclize to 1-oxa-2-sila-3-cyclobutenes 5 or form th
