6832-15-1Relevant articles and documents
TRANSFER OF THE DIAZO FUNCTION IN THE SERIES OF FLUORINATED 1,3-DIKETONES
Nikolaev, V. A.,Utkin, P. Yu.,Korobitsyna, I. K.
, p. 1059 - 1061 (2007/10/02)
In the reaction of fluorinated 1,3-diketones with p-toluenesulfonyl azide under the conditions of diazo transfer hydrolytic elimination of the perfluoroacyl group occurs, and acyldiazomethanes are formed instead of the fluorine-containing diazo diketones.The reaction can be used for the synthesis of difficultly obtainable and labile 2-diazo ketones.