123735-34-2

Basic information

• Product Name: (1S,2R,7R)-2-Benzyl-10,10-dimethyl-3-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-ene 3,3-dioxide
• CAS NO: 123735-34-2
• Molecular Weight: 303.425
• Mol File: 123735-34-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,2R,7R)-2-Benzyl-10,10-dimethyl-3-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-ene 3,3-dioxide(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R,7R)-2-Benzyl-10,10-dimethyl-3-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-ene 3,3-dioxide(123735-34-2)
• EPA Substance Registry System: (1S,2R,7R)-2-Benzyl-10,10-dimethyl-3-thia-4-aza-tricyclo[5.2.1.0^1,5]dec-4-ene 3,3-dioxide(123735-34-2)

Safety Data

• Hazardous Substances Data: 123735-34-2(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 60886-80-8 (1S)-(-)-camphorsulfonylimine 

Downstream Products

• 123735-35-3 C₁₇H₂₁NO₃S 
• 123735-35-3 (-)-<(4-exo-Benzylcamphoryl)sulfonyl>oxaziridine 

Relevant articles and documents

ENANTIOSELECTIVE SYNTHESIS OF (+)-KJELLMANIANONE

An asymmetric synthesis of the highly oxygenated cyclopentanoid antibiotic (+)-kjellmanianone (1) has been achieved.The key step entailed enantioselective hydroxylation of the prochiral sodium enolate of β-keto ester 2 with the new, enatiomerically pure N-sulfonyloxaziridine 7b, affording 1 in 68.5percent ee (60percent yield).Possible transition state structures for the asymmetric oxidation are evaluated.