123746-54-3Relevant academic research and scientific papers
Syntheses and Structures of NiS2N2 Compounds. nickel(II), Ni(tsalen), and nickel(II), Ni(ebmba)
Yamamura, Takeshi,Tadokoro, Makoto,Tanaka, Koji,Kuroda, Reiko
, p. 1984 - 1990 (1993)
The syntheses, structures, absorption spectra, and redox potentials of Ni(tsalen), H2tsalen=N,N'-bis(o-mercaptobenzyliden)ethylenediamine, and Ni(ebmba), H2ebmba=N,N'-bis(o-mercaptobenzyl)ethylenediamine, are described.Ni(tsalen) was prepared directly fro
HYDROGENATION OF ESTERS OR CARBONYL GROUPS WITH TETRADENTATE AMINO/IMINO-THIOETHER BASED RUTHENIUM COMPLEXES
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Paragraph 0144; 0148, (2013/10/22)
The present invention relates to the field of catalytic hydrogenation and, more particularly, to the use of specific ruthenium catalysts, or pre-catalysts, in hydrogenation processes for the reduction of ketones and/or aldehydes into the corresponding alcohol respectively. Said catalysts are ruthenium complexes comprising a tetradentate ligand (L4) coordinating the ruthenium with: two nitrogen atoms, each in the form of a primary or secondary amine (i.e. a NH2 or NH group) or N-alkyl imine functional groups (i.e. a C═N group), and two sulfur atoms, each in the form of thioether functional groups.
A New Synthetic Route and the Structural Analysis of Ni(tsalen). (N,N'-Ethylenebis(thiosalicylidenaminato))nickel(II)
Yamamura, Takeshi,Tadokoro, Makoto,Kuroda, Reiko
, p. 1245 - 1246 (2007/10/02)
A simple route to the nickel complex of thiosalen, Ni(tsalen), which is the correspondent of the classical salen compound, was developed.The molecular structure of Ni(tsalen) was studied also.
