123762-05-0

Basic information

• Product Name: 3-oxocyclohexancarboxyaldehyde ethylenacetal
• Synonyms: 3-oxocyclohexancarboxyaldehyde ethylenacetal
• CAS NO: 123762-05-0
• Molecular Weight: 170.208
• Mol File: 123762-05-0.mol

Chemical Properties

• CAS DataBase Reference: 3-oxocyclohexancarboxyaldehyde ethylenacetal(CAS DataBase Reference)
• NIST Chemistry Reference: 3-oxocyclohexancarboxyaldehyde ethylenacetal(123762-05-0)
• EPA Substance Registry System: 3-oxocyclohexancarboxyaldehyde ethylenacetal(123762-05-0)

Safety Data

• Hazardous Substances Data: 123762-05-0(Hazardous Substances Data)

Upstream product

• 28193-08-0 2-(3-cyclohexenyl)-1,3-dioxolane 
• 646-06-0 1,3-DIOXOLANE 
• 930-68-7 cyclohexenone 

Relevant articles and documents

Novel β-masked formylation of α,β-unsaturated ketones and lactones by tetra-n-butylammonium sulfate radical

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Photochemical Synthesis of 4-Oxobutanal Acetals and of 2-Hydroxycyclobutanone Ketals

Irradiation of α,β-unsaturated ketones (aliphatic, both open chain and cyclic as well as aryl substituted) in 1,3-dioxolane in the presence of a sensitizer (benzophenone or anthraquinone) led to 4-oxobutanal acetals in fair to excellent yield through a very simple procedure (workup in most cases by bulb-to-bulb distillation). The resulting acetals were irradiated to give 2-hydroxycyclobutanone ketals, again through a simple procedure that gave a good yield with open-chain aliphatic derivatives.

Practical β-masked formylation and acetylation of electron-deficient olefins utilizing tetra(n-butyl)ammonium peroxydisulfate

Various electron-deficient olefins reacted readily with 1,3-dioxolane or 2-methyl-1,3-dioxlane in the presence of TBAP to afford the corresponding 1,3-dioxolanylated or 2-methyl-1,3-dioxolanylated products in a complete regioselective manner in good to ex

FORMATION AND CHARACTERIZATION OF TETRABUTYLAMMONIUM SULFATE RADICAL: APPLICATION TO ORGANIC SYNTHESIS

n-Tetrabutylammonium Peroxydisulfate has been successfully synthesized and turned out to be a sulfate radical source which can be utilized for the efficient organic syntheses: chemoselective oxidations of alcohols to ketones, 2-tetrahydrofuranylation of a

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