123765-70-8Relevant articles and documents
Disulfide-Catalyzed Iodination of Electron-Rich Aromatic Compounds
Iida, Keisuke,Ishida, Shunsuke,Watanabe, Takamichi,Arai, Takayoshi
, (2019/06/13)
Herein, a disulfide-catalyzed electrophilic iodination of aromatic compounds using 1,3-diiodo-5,5-dimethylhydantoin (DIH) has been developed. The disulfide activates DIH as a Lewis base to promote the iodination reaction in acetonitrile under mild conditions. This system is applicable to a wide range of electron-rich aromatic compounds, including acetanilide, anisole, imidazole, and pyrazole derivatives.
Palladium-catalyzed ortho-halogenations of acetanilides with N-halosuccinimides via direct sp2 C–H bond activation in ball mills
Liu, Zi,Xu, Hui,Wang, Guan-Wu
supporting information, p. 430 - 435 (2018/02/27)
A solvent-free palladium-catalyzed ortho-iodination of acetanilides using N-iodosuccinimide as the iodine source has been developed under ball-milling conditions. This present method avoids the use of hazardous organic solvents, high reaction temperature,
Halogenation Using Quaternary Ammonium Polyhalides. XVII. Iodination of Acetanilide Derivatives with Benzyltrimethylammonium Dichloroiodate and Zinc Chloride
Kajigaeshi, Shoji,Kakinami, Takaaki,Watanabe, Fumiko,Okamoto, Tsuyoshi
, p. 1349 - 1351 (2007/10/02)
The reaction of acetanilide derivatives with benzyltrimethylammonium dichloroiodate in acetic acid in the presence of ZnCl2 at room temperature or at 70 deg C gave iodo-substituted acetanilide derivatives in good yields.
