1237745-24-2

Upstream product

• 174265-12-4 2-bromo-5-chlorobenzaldehyde 

Downstream Products

• 1237745-29-7 ((2,4,6-tri(tert-butyl)phenyl)B(C₁₀H₅Cl))2C₂H₂ 
• 1237745-30-0 ((2,4,6-tri(tert-butyl)phenyl)B(C₁₀H₅C₆H₄CH₃))2C₂H₂ 
• 1237745-31-1 ((2,4,6-tri(tert-butyl)phenyl)B(C₁₀H₅C₆H₄OMe))2C₂H₂ 
• 1309453-74-4 bis(para-thienyl) B-Mes* B-entacene 
• 1309453-83-5 bis(para-phenylacetylene) B-Mes* B-entacene 
• 1309453-81-3 bis(para-4-methoxyphenylethynyl) B-Mes* B-entacene 
• 1309453-80-2 C₇₈H₉₀B₂N₂ 
• 1309453-88-0 bis(para-TIPS-acetylene) B-Mes* B-entacene 
• 1309453-75-5 bis(para-ethynyl) B-Mes* B-entacene 

Relevant academic research and scientific papers

BORON-CONTAINING PI-ELECTRON MATERIALS INCORPORATING FORMALLY AROMATIC AND NEUTRAL BOREPIN RINGS

The synthesis, functionalization and characterization of borepin-based extended pi-electron molecules is disclosed. Bulky substituents shielded the vacant boron p-orbitals thus allowing synthetic manipulation and purification under ambient lab conditions.

Synthesis of functionalizable boron-containing π-electron materials that incorporate formally aromatic fused borepin rings

(Figure Presented) Not a natty B-OH: Borepin-based extended π-electron molecules contain bulky substituents that shield the vacant boron p orbitals and allow synthetic manipulation and purification under ambient conditions. These borepin-containing compounds (see picture; Mes* = 1,3,5-tris(tert-butyl) phenyl; B orange, C gray) display reversible cathodic electrochemistry and can be viewed as n-type analogues to bent acene hydrocarbons.