1237745-30-0

Upstream product

• 1237745-29-7 ((2,4,6-tri(tert-butyl)phenyl)B(C₁₀H₅Cl))2C₂H₂ 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 1237745-28-6 ((2,4,6-tri(tert-butyl)phenyl)B(C₁₀H₆))2C₂H₂ 
• 174265-12-4 2-bromo-5-chlorobenzaldehyde 
• 1237745-24-2 2,2'-(1Z,1'Z)-2,2'-(2,5-dibromo-1,4-phenylene)bis(ethene-2,1-diyl)bis(1-bromo-4-chlorobenzene) 
• 1237745-27-5 C₂H₂((CH₃)2SnC₁₀H₅Cl)2 

Relevant academic research and scientific papers

BORON-CONTAINING PI-ELECTRON MATERIALS INCORPORATING FORMALLY AROMATIC AND NEUTRAL BOREPIN RINGS

The synthesis, functionalization and characterization of borepin-based extended pi-electron molecules is disclosed. Bulky substituents shielded the vacant boron p-orbitals thus allowing synthetic manipulation and purification under ambient lab conditions.

Synthesis of functionalizable boron-containing π-electron materials that incorporate formally aromatic fused borepin rings

(Figure Presented) Not a natty B-OH: Borepin-based extended π-electron molecules contain bulky substituents that shield the vacant boron p orbitals and allow synthetic manipulation and purification under ambient conditions. These borepin-containing compounds (see picture; Mes* = 1,3,5-tris(tert-butyl) phenyl; B orange, C gray) display reversible cathodic electrochemistry and can be viewed as n-type analogues to bent acene hydrocarbons.