123827-08-7Relevant academic research and scientific papers
Use of Radical Ring-Opening for Introduction of Alkyl and Substituted Alkyl Groups with Stereochemical Control: A Synthetic Application of Cyclopropylcarbinyl Radicals
Clive, Derrick L. J.,Daigneault, Sylvain
, p. 3801 - 3814 (2007/10/02)
Cyclopropylcarbinols 2a and 2b (see Scheme I), which are accessible by a number of routes, can be converted into the corresponding radicals 3a and 3b, respectively.These radicals undergo peripheral ring-opening of the cyclopropyl substructure to afford su
Synthetic Applications of Radical Ring-Opening: Use of Cyclopropylmethyl Radicals
Clive, Derrick L. J.,Daigneault, Sylvain
, p. 332 - 335 (2007/10/02)
Cycloropanation of cyclic allylic alcohols followed by radical deoxygenation leads, by peripheral ring-opening of the cyclopropylmethyl system, to alkyl-substituted cycloalkenes (Scheme 1); the alkyl group can itself be substituted (during the cyclopropan
