123848-41-9

Basic information

• Product Name: 2-(3-methylphenyl)-1,2-diphenylethanone
• Synonyms: 2-(3-methylphenyl)-1,2-diphenylethanone
• CAS NO: 123848-41-9
• Molecular Weight: 286.373
• Mol File: 123848-41-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2-(3-methylphenyl)-1,2-diphenylethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3-methylphenyl)-1,2-diphenylethanone(123848-41-9)
• EPA Substance Registry System: 2-(3-methylphenyl)-1,2-diphenylethanone(123848-41-9)

Safety Data

• Hazardous Substances Data: 123848-41-9(Hazardous Substances Data)

Upstream product

• 26926-53-4 2-phenyl-2-(m-tolyl)acetonitrile 
• 447-31-4 Desyl chloride 
• 52056-23-2 2-hydroxy-1,2-diphenyl-2-m-tolyl-ethanone 
• 451-40-1 phenyl benzyl ketone 
• 108-41-8 1-chloro-3-methylbenzene 
• 99-08-1 1-methyl-3-nitrobenzene 
• 625-95-6 3-Iodotoluene 
• 7664-93-9 sulfuric acid 
• 110247-83-1 (1RS,2RS)-1,2-diphenyl-1-m-tolyl-ethane-1,2-diol 
• 110247-83-1 1,2-Diphenyl-1-m-tolyl-ethane-1,2-diol 
• 110248-47-0 1,1-diphenyl-2-m-tolyl-ethane-1,2-diol 

Relevant articles and documents

Method for preparing alpha-aryl ketone compound by using palladium complex

The invention relates to a method for preparing an alpha-aryl ketone compound by using a palladium complex, which comprises the steps of in the presence of alkali, taking ketone and halogenated hydrocarbon as raw materials, taking the palladium complex containing an ortho-carborane benzothiazole structure as a catalyst, and carrying out alpha-halogenation reaction at room temperature to prepare the alpha-aryl ketone compound. Compared with the prior art, the palladium complex containing the ortho-carborane benzothiazole structure is applied to catalysis of the alpha-halogenation reaction of ketone and halogenated hydrocarbon, the alpha-aryl substituted ketone compound is prepared through a one-pot method, synthesis of the alpha-aryl ketone compound at room temperature by using simple, easily available and cheap raw materials is achieved, and the method has the advantages of low catalyst use equivalent, mild reaction conditions, more catalytic substrates, high substrate universality and high yield.

Metal Free, Direct and Selective Deoxygenation of α-Hydroxy Carbonyl Compounds: Access to α,α-Diaryl Carbonyl Compounds

An efficient, metal free, direct and selective deoxygenation of α-hydroxy carbonyl compounds is achieved with the aid of catalytic amount of aqueous HClO4 (70 %) and triethylsilane as hydride source. A variety of α-hydroxy-α,α-diaryl carbonyl compounds are selectively deoxygenated to give α,α-diaryl carbonyl compounds in good to excellent yields. Intermediacy of α-keto carbenium ion is proposed on the basis of some control experiments and atmospheric pressure chemical ionization mass spectral analysis.

PROCESS FOR CREATING CARBON-CARBON BONDS USING CARBONYL COMPOUNDS

The present invention concerns a process for preparing a compound of formula (I) by reaction between a compound of formula (II) and a compound of formula (III) in the presence of a copper-containing catalyst, a ligand and base. The invention also concerns the implementing of this process for the preparation of building blocks to prepare molecules of interest in particular in the pharmaceutical, agro-chemical fields, etc.