1238675-78-9Relevant academic research and scientific papers
Stoichiometry of the reaction of diphenylchlorophosphine with dimethylformamide in the presence of NaI
Morgalyuk,Petrovskii,Lysenko,Nifant'Ev
, p. 100 - 105 (2010)
Stoichiometric relations of initial compounds and reaction products in the synthesis of N,N-dialkyl-(diphenylphosphinomethylene)iminium are established; the second reaction product is diphenylphosphinic iodide. Bringing triphenylphosphine into the reaction increases the N,N- dialkyl(diphenylphosphinomethylene)-iminium yield approximately twice. One of the reaction intermediates is shown to be iododiphenylphosphine. The reaction can be regarded as disproportionation.
