1239307-35-7Relevant academic research and scientific papers
A facile route to functionalized N-heterocyclic carbenes (NHCs) with NHC base-stabilized dichlorosilylene
Ghadwal, Rajendra S.,Roesky, Herbert W.,Granitzka, Markus,Stalke, Dietmar
supporting information; experimental part, p. 10018 - 10020 (2010/10/03)
Reaction of IPr·SiCl2 (1) [IPr) 1,3-bis(2,6- diisopropylphenyl)imidazol-2-ylidene] with 1-azidoadamantane leads to functionalized N-heterocyclic carbene (NHC) 2. Silyl-substituted NHC 2 reacts easily with 1-azidoadamantane to form triazene 3, in which the exocyclic CdN bond is slightly shorter than those of regular NHC-derived triazines. 2 could serve as a promising ligand for transition metals.
