24886-73-5

Basic information

• Product Name: 1-AZIDOADAMANTANE 97
• Synonyms: 1-AZIDOADAMANTANE 97;1-AZIDOADAMANTANE 97%;(1-Adamantyl) azide;1-Adamantyl azide;Adamantane-1-yl azide
• CAS NO: 24886-73-5
• Molecular Formula: C₁₀H₁₅N₃
• Molecular Weight: 177.2462
• Product Categories: AChemical Ligation;Click Chemistry;Organic Azides;Stains and Dyes;Stains&Dyes, A to
• Mol File: 24886-73-5.mol

Chemical Properties

• Melting Point: 80-82 °C(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: 85 °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: 1-AZIDOADAMANTANE 97(CAS DataBase Reference)
• NIST Chemistry Reference: 1-AZIDOADAMANTANE 97(24886-73-5)
• EPA Substance Registry System: 1-AZIDOADAMANTANE 97(24886-73-5)

Safety Data

• Hazard Codes: F
• Statements: 11
• Safety Statements: 16-33
• RIDADR: 1325
• WGK Germany: 3
• HazardClass: 4.1
• PackingGroup: III
• Hazardous Substances Data: 24886-73-5(Hazardous Substances Data)

Usage

Type of compound

Highly reactive organic azide

Structure

Rigid adamantane cage with an azide group attached

Common uses

a. Synthesis of various organic compounds
b. Production of energetic materials (explosives, propellants, pyrotechnics)
c. Precursor in organic synthesis for introducing azide functionality

Known for

Explosive nature

Safety precautions

Requires careful handling and storage to prevent accidents

InChI:InChI=1/C10H15N3/c11-13-12-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9H,1-6H2

Upstream product

• 110-86-1 pyridine 
• 281-23-2 adamantane 
• 1013632-22-8 methyl 1-adamantylcarbonyloxy(phenyl)carbamodithioate 

Downstream Products

• 55086-02-7 6-hydroxy-5-azatricyclo<4.3.1.1^3,8>undecane 
• 78837-35-1 3-Cyano-4-azahomoadamantane 
• 76599-37-6 1-(adamantan-1-yl)-4-phenyl-1H-[1,2,3]-triazole 
• 76599-36-5 1-(1-adamantyl)-5-phenyl-1H-1,2,3-triazole 
• 129811-67-2 4-(1-Adamantyl)-5-chloro-4,5-dihydro-1-(2,4,6-tri-tert-butylphenyl)-1H-tetrazaphosphole 
• 768-95-6 1-adamanthanol 
• 768-94-5 1-Adamantanamine 
• 76036-40-3 3-m-Tolyl-4-aza-tricyclo[4.3.1.1^3,8]undecane 
• 75470-72-3 3-p-Tolyl-4-aza-tricyclo[4.3.1.1^3,8]undecane 
• 75470-71-2 3-o-Tolyl-4-aza-tricyclo[4.3.1.1^3,8]undecane 
• 76036-39-0 3-Phenyl-4-aza-tricyclo[4.3.1.1^3,8]undecane 
• 780-68-7 1-phenyladamantane 
• 665-66-7 amantadine hydrochloride 
• 78822-94-3 4-Imino-5-phenyl-5,7-diazatetracyclo<7.3.1.1^3,11.0^3,7>tetradecan-6-one 

Relevant articles and documents

Decarboxylative radical azidation using MPDOC and MM DOC esters

An efficient radical-mediated decarboxylative azidation of aliphatic carboxylic acids has been developed. The success of this transformation hinges on the use of a new type of thiohydroxamate esters (MPDOC esters). These esters are more stable than the cl

The Functionalization of Saturated Hydrocarbons. Part 26. Ionic Substitution Reactions in GoAggIV Chemistry: The Construction of C-N, C-S and C-C Bonds

Utilization of the GoAggIV system in the presence of sodium azide, sodium nitrite, sodium thiocyanate, sodium disulfide and tetraethylammonium cyanide converts saturated hydrocarbons into the corresponding alkyl azides, nitroalkanes, alkyl thiocyanates, dialkyl disulfides and alkyl cyanides, respectively.Mechanistic studies suggest an Fe-centered ligand coupling reaction pathway.Key Words: Gif systems; Selective functionalization, Iron catalysts, C-N bond formation, C-S bond formation, C-C bond formation