12399-55-2Relevant articles and documents
Potentiometric Studies on Sulfato Complex of Aluminium(III) in Aqueous Solution at Elevated Temperatures
Matsushima, Yoshiyuki,Matsunaga, Akio,Sakai, Kazuhiro,Okuwaki, Akitsugu
, p. 4259 - 4264 (1988)
Equilibria in aluminium sulfate solutions with a 1 mol kg-1 KCl medium and low pH range have been investigated by means of acidity measurements with a hydrogen ion concentration cell from 25 to 125 deg C.The results were treated with a nonlinear least squares computer program to analyze the equilibrium constants for aluminium complexes by using a single parameter type of Debye-Hueckel equation.The log(K/mol-1 kg) values of the formation constant for the reaction, Al3++SO42-->/+ varied from 3.35 at 25 deg C to 5.34 at 125 deg C and were formulated as a function of temperature.The standard enthalpy and entropy of the complex formation computed from the variation of the formation constant with temperature are presented over the experimental temperature range.The species - was not detected under the present conditions.