123993-70-4

Upstream product

• 124095-80-3 (E)-(R*,S*)-5-chloro-3-hexen-2-yl acetate 
• 18522-92-4 sodium p-toluenesulfonamide 

Downstream Products

• 81330-01-0 cis-N-(p-toluenesulfonyl)-2,5-dimethylpyrrolidine 
• 123993-97-5 trans-N-(p-toluenesulfonyl)-2,5-dimethylpyrrolidine 
• 123993-81-7 (R*,S*)-2-(p-toluenesulfonamido)hexan-5-ol 
• 123993-89-5 (R*,S*)-2-(mesyloxy)-5-(p-toluenesulfonamido)hexane 
• 143707-57-7 (2S*,3R*,4S*,5S*)-2-<(tert-butyldimethylsilyl)oxy>-3,4-epoxy-5-(tosylamido)hexane 
• 143707-57-7 (2S*,3S*,4R*,5S*)-2-<(tert-butyldimethylsilyl)oxy>-3,4-epoxy-5-(tosylamido)hexane 
• 143707-59-9 (2S*,3R*,4S*,5R*)-3,4-epoxy-5-(N-methyltosylamido)hexan-2-ol 
• 123993-74-8 (E)-(R*,S*)-2-(p-toluenesulfonamido)-3-hexen-5-ol 

Relevant academic research and scientific papers

A Stereocontrolled Organopalladium Route to 2,5-Disubstituted Pyrrolidine Derivatives. Application to the Synthesis of a Venom Alkaloid of the Ant Species Monomorium latinode

A general method for the preparation of cis- and trans-2,5-disubstituted pyrrolidines from conjugated dienes has been developed.The approach involves a stereocontrolled syn- or anti-1,4-addition of an amino and an oxygen function to the diene via palladiu

SYNTHESIS OF PROTECTED ALLYLAMINES VIA PALLADIUM-CATALYZED AMIDE ADDITION TO ALLYLIC SUBSTRATES

Palladium-catalyzed reaction of allylic substrates with sodium p-toluenesulfonamide leads to the N-allylic-p-toluenesulfonamides.The reaction takes place with retention of configuration at the allylic carbon.