A Stereocontrolled Organopalladium Route to 2,5-Disubstituted Pyrrolidine Derivatives. Application to the Synthesis of a Venom Alkaloid of the Ant Species Monomorium latinode

DOI: 10.1021/jo00290a010

Source and publish data:

Journal of Organic Chemistry p. 826 - 831 (1990)

Update date:2022-09-26

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Authors:

Baeckvall, Jan-E.

Schink, Hans E.

Renko, Z. Dolor

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Article abstract of DOI:10.1021/jo00290a010

A general method for the preparation of cis- and trans-2,5-disubstituted pyrrolidines from conjugated dienes has been developed.The approach involves a stereocontrolled syn- or anti-1,4-addition of an amino and an oxygen function to the diene via palladiu

Full text of DOI:10.1021/jo00290a010

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