123994-89-8Relevant academic research and scientific papers
A SELECTIVE BASE-INDUCED REARRANGEMENT OF PERHYDRONAPHTHALANES TO 1,5-CIS-FUSED 10-METHYLENE PERHYDROAZULENES
Wijnberg, Joannes B. P. A.,Groot, Ae. de
, p. 3007 - 3010 (1987)
The rearrangement of perhydronaphthalenic tosylate 3 to 1,5-cis 10-methylene perhydroazulene 4 was achived selectively and in high yield via intramolecular assistance of a 4β hydroxylate.
Base-Induced and -Directed Rearrangements of 4-Monotosylated Perhydronaphthalene-1,4-diols. Synthesis of (+/-)-5-epi-Nardol
Wijnberg, Joannes B. P. A.,Jenniskens, Louis H. D.,Brunekreef, Gerd A.,Groot, Aede de
, p. 941 - 948 (2007/10/02)
The utility of perhydronaphthalene precursors for the synthesis of sesquiterpenes which possess a cis-fused perhydroazulene skeleton with an exocyclic methylene unit has been examined.For this purpose the tosylates 3, 4, 28, and 29 were prepared, and thei
