A SELECTIVE BASE-INDUCED REARRANGEMENT OF PERHYDRONAPHTHALANES TO 1,5-CIS-FUSED 10-METHYLENE PERHYDROAZULENES

DOI: 10.1016/S0040-4039(00)96269-5

Source and publish data:

Tetrahedron Letters p. 3007 - 3010 (1987)

Update date:2022-09-26

Topics:

Authors:

Wijnberg, Joannes B. P. A.

Groot, Ae. de

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Article abstract of DOI:10.1016/S0040-4039(00)96269-5

The rearrangement of perhydronaphthalenic tosylate 3 to 1,5-cis 10-methylene perhydroazulene 4 was achived selectively and in high yield via intramolecular assistance of a 4β hydroxylate.

Full text of DOI:10.1016/S0040-4039(00)96269-5

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