A SELECTIVE BASE-INDUCED REARRANGEMENT OF PERHYDRONAPHTHALANES TO 1,5-CIS-FUSED 10-METHYLENE PERHYDROAZULENES

DOI: 10.1016/S0040-4039(00)96269-5

Source and publish data:

Tetrahedron Letters p. 3007 - 3010 (1987)

Update date:2022-09-26

Topics:

Authors:

Wijnberg, Joannes B. P. A.

Groot, Ae. de

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96269-5

The rearrangement of perhydronaphthalenic tosylate 3 to 1,5-cis 10-methylene perhydroazulene 4 was achived selectively and in high yield via intramolecular assistance of a 4β hydroxylate.

Full text of DOI:10.1016/S0040-4039(00)96269-5

Products guided by the article

Product name:(4aα,5α,8α,8aβ)-octahydro-5,8-dihydroxy-4a,8-dimethyl-2(1H)-naphthalenone 5-(4-methylbenzenesulfonate)

Cas No:123994-89-8

R&D Labs maybe for 123994-89-8

Geen Chemical Technology Co., Ltd

Contact:86-769-21660847

Address:1408, Yingfeng Commercial Center, Nancheng District
Shandong Dayi Chemical Co., Ltd.

website:http://www.dayi.com.cn

Contact:+86- 535-7388728. 15306386031

Address:No 1 Danya west road, Laiyang City, Shandong province
Baoding City Light Industry And Textiles Imp.& Exp. Corp. Chemical Department.

Contact:86-312-3262436

Address:NO.658 CHAOYANG SOUTH STREET,BAODING CITY HEBEI CHINA
Shanghai Sungo Technology Chemical Co., Ltd

Contact:0086-21-51385579

Address:Room2010, F/20, Tonghua Plaza, NO 345 Jinxiang Road, Jinqiao Export Processing Zone, Shanghai, 201206 P.R.CHINA
Jiangsu Willing Bio-Tech Co ltd

website:http://www.willingbio.com/

Contact:+86 18796908173

Address:No 18 Guoqiao Road

Relevant to this article

Synthesis of 7-(4-piperidyl)- [1,6]naphthyridin-5-one and 3-(4-piperidyl)isoqunolin-1-one

Doi:10.1007/s10593-010-0457-6
(2009)
CAAC boranes. synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF₃ and BH₃

Doi:10.3762/bjoc.6.82
(2010)
Access to B=S and B=Se double bonds via sulfur and selenium insertion into a B-H bond and hydrogen migration

Doi:10.1021/ja105021d
(2010)
Development of a highly selective,orally bioavailable and CNS penetrant M1 agonist derived from the MLPCN probe ML071

Doi:10.1016/j.bmcl.2011.08.084
(2011)
on-water organic synthesis: L-proline catalyzed synthesis of pyrimidine-2,4-dione-, benzo[g]- and dihydropyrano[2,3-g]chromene derivatives in aqueous media

Doi:10.1007/s13738-012-0160-x
(2013)
Synthesis of a C-glucosylated cyclopropylamide and evaluation as a glycogen phosphorylase inhibitor

Doi:10.1016/j.bmcl.2008.07.098
(2008)

Article Doi