A SELECTIVE BASE-INDUCED REARRANGEMENT OF PERHYDRONAPHTHALANES TO 1,5-CIS-FUSED 10-METHYLENE PERHYDROAZULENES

DOI: 10.1016/S0040-4039(00)96269-5

Source and publish data:

Tetrahedron Letters p. 3007 - 3010 (1987)

Update date:2022-09-26

Topics:

Authors:

Wijnberg, Joannes B. P. A.

Groot, Ae. de

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96269-5

The rearrangement of perhydronaphthalenic tosylate 3 to 1,5-cis 10-methylene perhydroazulene 4 was achived selectively and in high yield via intramolecular assistance of a 4β hydroxylate.

Full text of DOI:10.1016/S0040-4039(00)96269-5

Products guided by the article

Product name:(4aα,5α,8α,8aβ)-octahydro-5,8-dihydroxy-4a,8-dimethyl-2(1H)-naphthalenone 5-(4-methylbenzenesulfonate)

Cas No:123994-89-8

R&D Labs maybe for 123994-89-8

Shanghai Sinofluoro Scientific Co., Ltd

Contact:+86-21-64279360

Address:Room 1006,Building 3,#58 East Xinjian Road, Shanghai ,201100,China,
Heliosense Biotechnologies, Inc.

website:https://www.heliosense.com/

Contact:+86-592-5667290

Address:Xiamen Torch Hi-tech Zone Venture Weiye Building S506
Shandong Shouguang Songchuan Industrial Additives Co.,Ltd

Contact:+86-536-8566856

Address:Shouguang,Shandong,China
SHANDONG CREDAGRI CHEMICAL CO., LTD.

Contact:+86-531-88872050

Address:ROOM 601A, BUILDING 2, SHUNTAI SQUARE, NO. 2000 SHUNHUA ROAD, HI-TECH DEVELOPMENT ZONE, JINAN, CHINA.
SunaTech Inc.

Contact:+86 512 6287 2180

Address:398 Ruoshui Road, Suzhou Industrial Park, Suzhou, Jiangsu, P. R. China

Relevant to this article

Synthesis of 7-(4-piperidyl)- [1,6]naphthyridin-5-one and 3-(4-piperidyl)isoqunolin-1-one

Doi:10.1007/s10593-010-0457-6
(2009)
CAAC boranes. synthesis and characterization of cyclic (alkyl) (amino) carbene borane complexes from BF₃ and BH₃

Doi:10.3762/bjoc.6.82
(2010)
Access to B=S and B=Se double bonds via sulfur and selenium insertion into a B-H bond and hydrogen migration

Doi:10.1021/ja105021d
(2010)
Development of a highly selective,orally bioavailable and CNS penetrant M1 agonist derived from the MLPCN probe ML071

Doi:10.1016/j.bmcl.2011.08.084
(2011)
on-water organic synthesis: L-proline catalyzed synthesis of pyrimidine-2,4-dione-, benzo[g]- and dihydropyrano[2,3-g]chromene derivatives in aqueous media

Doi:10.1007/s13738-012-0160-x
(2013)
Synthesis of a C-glucosylated cyclopropylamide and evaluation as a glycogen phosphorylase inhibitor

Doi:10.1016/j.bmcl.2008.07.098
(2008)

Article Doi