1239986-59-4Relevant academic research and scientific papers
Mechanochemical Rhodium(III)-Catalyzed C-H Bond Amidation of Arenes with Dioxazolones under Solventless Conditions in a Ball Mill
Hermann, Gary N.,Bolm, Carsten
, p. 4592 - 4596 (2017/07/24)
A procedure for the direct mechanochemical rhodium(III)-catalyzed C-H bond amidation of arenes with 1,4,2-dioxazol-5-ones as the nitrogen source has been developed. The transformation proceeds under solventless conditions and does not require additional h
Palladium-catalyzed oxidative C-H bond coupling of steered acetanilides and aldehydes: A facile access to ortho -acylacetanilides
Wu, Yinuo,Li, Baozhu,Mao, Fei,Li, Xingshu,Kwong, Fuk Yee
supporting information; experimental part, p. 3258 - 3261 (2011/08/05)
A palladium-catalyzed oxidative C-H bond functionalization/ortho-acylation of acetanilides using easily accessible aldehyde as the acyl source is described. In the presence of a Pd(TFA)2 catalyst and tert-butylhydroperoxide at 90 °C in general, an array of ortho-acylacetanilides can be afforded in good yields.
Palladium-catalyzed ortho-acylation of acetanilides with aldehydes through direct Ci-H bond activation
Li, Chengliang,Wang, Lei,Li, Pinhua,Zhou, Wei
supporting information; experimental part, p. 10208 - 10212 (2011/10/31)
Easy access to o-acyl acetanilides: A new Pd-catalyzed ortho-acylation of acetanilides with both aromatic and aliphatic aldehydes has been developed based on a Ci-H activation process. In the presence of tert-butyl hydroperoxide (TBHP) as the ideal oxidant, this reaction provides an efficient access to ortho-acyl acetanilides in good yields (see scheme). Copyright
Room temperature palladium-catalyzed decarboxylative ortho -acylation of acetanilides with α-oxocarboxylic acids
Fang, Ping,Li, Mingzong,Ge, Haibo
scheme or table, p. 11898 - 11899 (2010/11/02)
A novel Pd-catalyzed decarboxylative ortho-acylation of acetanilides with α-oxocarboxylic acids is realized at room temperature. This reaction provides efficient access to o-acyl acetanilides under mild conditions.
