1240069-62-8Relevant articles and documents
Synthesis of functionalized resorcinols by rhodium-catalyzed [5+1] cycloaddition reaction of 3-acyloxy-1,4-enynes with CO
Brancour, Celia,Fukuyama, Takahide,Ohta, Yuko,Ryu, Ilhyong,Dhimane, Anne-Lise,Fensterbank, Louis,Malacria, Max
, p. 5470 - 5472 (2010)
A novel [5+1] type carbonylative cycloaddition reaction has been developed using a Rh complex as catalyst. This reaction can convert readily available 3-acyloxy-1,4-enynes and CO to a wide range of functionalized resorcinols in good yields. A mechanism involving Rh-catalyzed cyclocarbonylation of 3-acyloxy-1,4-enynes accompanied by a 1,2-acyloxy shift is proposed for the present [5+1] type cycloaddition reaction. The Royal Society of Chemistry 2010.