124008-59-9Relevant academic research and scientific papers
The effects of in-situ trimethylsilyl chloride on the regioselectivity of the addition of α-alkoxy- and α-alkyl-substituted organocuprates to enals
Linderman, Russel J.,McKenzie, Joyce R.
, p. 31 - 42 (1989)
The regioselectivity of the addition of α-substituted organocuprates to enals has been examined.The addition of trimethylsilyl chloride to both the enal and cuprate prior to the combination of the reactants improves the regioselectivity and the isolated y
Highly Selective Syn Acyclic Homoaldol Chemistry Sythesis of cis-3,4-Disubstituted Butyrolactones
Linderman, Russell J.,McKenzie, Joyce R.
, p. 3911 - 3914 (2007/10/02)
Syn acyclic homoaldol products have been prepared by the conjugate addition reaction of α-alkoxyorganocuprates to enals.Selectivities of up to > 250:1 have been obtained.
