1240505-17-2Relevant articles and documents
(2-Fluoroallyl)boronates: New reagents for diastereoselective 2-fluoroallylboration of aldehydes
Novikov, Maxim A.,Nefedov, Oleg M.
, p. 4963 - 4967 (2018)
A Pd-catalyzed borylation of 2-fluoroallyl chlorides with B2pin2 in the presence of [(2-MeAll)PdCl]2/TMEDA or [(2-MeAll)Pd(IPr)Cl] was developed to afford (2-fluoroallyl)pinacolboronates with high Z-selectivity. The products proved to be useful for anti-selective 2-fluoroallylboration of aromatic and aliphatic aldehydes.