1240520-49-3Relevant articles and documents
Silver-catalyzed benzylation and allylation of tertiary alkyl bromides with organozinc reagents
Mitamura, Yukihiro,Asada, Yoshihiro,Murakami, Kei,Someya, Hidenori,Yorimitsu, Hideki,Oshima, Koichiro
, p. 1487 - 1493 (2011/07/07)
Silver salts catalyze the benzylation and allylation of tertiary alkyl bromides with organozinc reagents. The reactions create quaternary carbon centers efficiently. Treatment of gem-dibromoalkanes with benzylic or allylic zinc reagents under silver catalysis leads to dibenzylation or diallylation. The functional-group compatibility of the present reactions is wider than that of the previous reactions with Grignard reagents.