1240554-72-6

Upstream product

• 145381-23-3 (p-cymene)RuCl2(PCy3) 
• 1240554-71-5 1-(3,5-dimethoxyphenyl)-1-phenylprop-2-yn-1-ol 
• 52462-29-0 [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 
• 2622-14-2 tricyclohexylphosphine 
• 628263-26-3 (3,5-dimethoxyphenyl)(phenyl)methanone 
• 19179-31-8 3,5-dimethoxy-benzonitrile 
• 100-59-4 phenylmagnesium chloride 
• 15529-49-4 tris(triphenylphosphine)ruthenium(II) chloride 

Relevant academic research and scientific papers

A most convenient and atom-economic preparation of a highly active ring-closing metathesis catalyst

A new olefin metathesis catalyst has been prepared in situ by a one-step method utilizing an easy-to-prepare organic precursor and only 1 equiv of tricyclohexylphosphine ligand per ruthenium atom. The activity of the new catalytic system for the formation of five-, six-, and seven-membered disubstituted cycloalkenes via ring-closing metathesis under standard conditions is comparable to that of related highly active commercial catalysts.

METHOD FOR IN-SITU FORMATION OF METATHESIS CATALYSTS

Synthetic methods for the in-situ formation of olefin metathesis catalysts are disclosed, as well as the use of such catalysts in metathesis reactions of olefins and olefin compounds. In one aspect, a method is provided for synthesizing an organometallic