1240554-72-6Relevant academic research and scientific papers
A most convenient and atom-economic preparation of a highly active ring-closing metathesis catalyst
Jimenez, Leonel R.,Gallon, Benjamin J.,Schrodi, Yann
, p. 3471 - 3473 (2010)
A new olefin metathesis catalyst has been prepared in situ by a one-step method utilizing an easy-to-prepare organic precursor and only 1 equiv of tricyclohexylphosphine ligand per ruthenium atom. The activity of the new catalytic system for the formation of five-, six-, and seven-membered disubstituted cycloalkenes via ring-closing metathesis under standard conditions is comparable to that of related highly active commercial catalysts.
METHOD FOR IN-SITU FORMATION OF METATHESIS CATALYSTS
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Page/Page column 31-32, (2011/10/13)
Synthetic methods for the in-situ formation of olefin metathesis catalysts are disclosed, as well as the use of such catalysts in metathesis reactions of olefins and olefin compounds. In one aspect, a method is provided for synthesizing an organometallic
