100-59-4

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Basic information

Product Name: PHENYLMAGNESIUM CHLORIDE
Synonyms: PHENYLMAGNESIUM CHLORIDE, 2.0M SOLUTION IN TETRAHYDROFURAN;Phenylmagnesium Chloride 2.0 M In Tetrahdyrofuran;PHENYLMAGNESIUM CHLORIDE 25 WT% IN THF;Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran;PHENYLMAGNESIUM CHLORIDE, 1 M in DIBUTYL ETHER;PHENYLMAGNESIUM CHLORIDE, 2 M in TETRAHYDROFURAN;Phenylmagnesiumchloride,2-3MinTHF;PHENYLMAGNESIUMCHLORIDE,25%INTETRAHYDROFURAN
CAS NO:100-59-4
Molecular Formula: C₆H₅ClMg
Molecular Weight: 136.86
EINECS: 202-868-8
Product Categories: Organometallics;Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Aryl;Grignard Reagents;Organometallic Reagents;grignard reagent
Mol File: 100-59-4.mol
Article Data: 8

Chemical Properties

Melting Point: 89-90℃
Boiling Point: 230℃ (8 Torr)
Flash Point: 1 °F
Appearance: yellowish-brown to dark brown solution
Density: 0.98 g/mL at 20 °C
Vapor Pressure: 101mmHg at 25°C
Refractive Index: N/A
Storage Temp.: water-free area
Solubility: N/A
Water Solubility: It reacts violently with water.
Sensitive: Air & Moisture Sensitive
Merck: 14,7298
BRN: 3587900
CAS DataBase Reference: PHENYLMAGNESIUM CHLORIDE(CAS DataBase Reference)
NIST Chemistry Reference: PHENYLMAGNESIUM CHLORIDE(100-59-4)
EPA Substance Registry System: PHENYLMAGNESIUM CHLORIDE(100-59-4)

Safety Data

Hazard Codes: F,C
Statements: 14-19-20/21/22-34-67-65-63-48/20-11-40-37
Safety Statements: 26-36/37/39-45-62-33-16
RIDADR: UN 2924 3/PG 2
WGK Germany: 2
RTECS:
F: 10
TSCA: Yes
HazardClass: 8
PackingGroup: II
Hazardous Substances Data: 100-59-4(Hazardous Substances Data)

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Well-known Company Product Price
SDS
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Product	FOB Price	Min.Order	Supply Ability	Supplier
Phenylmagnesium chloride Manufacturer/High quality/Best price/In stock Cas No: 100-59-4	USD $ 3.0-3.0 / Kilogram	1 Kilogram	1-100 Metric Ton/Month	Dayang Chem (Hangzhou) Co.,Ltd.	Contact Supplier
High quality Phenylmagnesium Chloride supplier in China Cas No: 100-59-4	No Data	1 Metric Ton	30 Metric Ton/Month	Simagchem Corporation	Contact Supplier
Phenylmagnesium chloride Cas No: 100-59-4	USD $ 1.0-2.0 / Metric Ton	1 Metric Ton	100 Metric Ton/Week	Hebei yanxi chemical co.,LTD.	Contact Supplier
Factory Supply Chlorophenylmagnesium Cas No: 100-59-4	No Data	1	1	Ality Chemical Corporation	Contact Supplier
Phenylmagnesium chloride Cas No: 100-59-4	USD $ 1.2-5.0 / Kiloliter	5 Kiloliter	3000 Metric Ton/Month	Chemwill Asia Co., Ltd.	Contact Supplier
TIANFU-CHEM PHENYLMAGNESIUM CHLORIDE 100-59-4 Cas No: 100-59-4	No Data	1 Kilogram	10 Metric Ton/Month	Henan Tianfu Chemical Co., Ltd.	Contact Supplier
PHENYLMAGNESIUM CHLORIDE Cas No: 100-59-4	USD $ 9.0-99.0 / Kilogram	1 Kilogram	1 Kilogram/Month	Hebei Nengqian Chemical Import and Export Co., LTD	Contact Supplier
Wholesale price CAS 100-59-4 with best price Cas No: 100-59-4	USD $ 139.0-210.0 / Kilogram	1 Kilogram	1000 Kilogram/Day	Zhuozhou Wenxi import and Export Co., Ltd	Contact Supplier
Magnesium,chlorophenyl- 100-59-4 Cas No: 100-59-4	No Data	1 Kilogram	10000 Metric Ton/Month	Shanghai Upbio Tech Co.,Ltd	Contact Supplier
PHENYLMAGNESIUM CHLORIDE in THF solution Cas No: 100-59-4	No Data	1 Gram	100 Kilogram/Day	Shanghai Minstar Chemical Co., Ltd	Contact Supplier

100-59-4 Usage

Chemical Properties

yellowish-brown to dark brown solution

Uses

Different sources of media describe the Uses of 100-59-4 differently. You can refer to the following data:
1. In organic synthesis, especially in the production of hydrocarbons, alcohols, ketones, organic acids, amines, silicones, boranes.
2. Phenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of (?)-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl3) in the rechargeable magnesium batteries.
3. Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

General Description

This product has been enhanced for energy efficiency.

Check Digit Verification of cas no

The CAS Registry Mumber 100-59-4 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 0 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 100-59:
(5*1)+(4*0)+(3*0)+(2*5)+(1*9)=24
24 % 10 = 4
So 100-59-4 is a valid CAS Registry Number.

InChI:InChI=1/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q-1;;+2/p-1

100-59-4 Well-known Company Product Price

Brand	(Code)Product description	CAS number	Packaging	Price	Detail
TCI America	(P1381) Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L)	100-59-4	250g	640.00CNY	Detail
Alfa Aesar	(H51157) Phenylmagnesium chloride, 1M in MeTHF	100-59-4	100ml	483.0CNY	Detail
Alfa Aesar	(H51157) Phenylmagnesium chloride, 1M in MeTHF	100-59-4	500ml	1208.0CNY	Detail
Aldrich	(775045) Phenylmagnesiumchloridesolution 1.0 M in 2-methyltetrahydrofuran	100-59-4	775045-100ML	331.11CNY	Detail
Aldrich	(775045) Phenylmagnesiumchloridesolution 1.0 M in 2-methyltetrahydrofuran	100-59-4	775045-4X25ML	387.27CNY	Detail
Aldrich	(775045) Phenylmagnesiumchloridesolution 1.0 M in 2-methyltetrahydrofuran	100-59-4	775045-800ML	1,645.02CNY	Detail
Aldrich	(257125) Phenylmagnesiumchloridesolution 2.0 M in THF	100-59-4	257125-200ML	1,503.45CNY	Detail
Aldrich	(224448) Phenylmagnesiumchloridesolution 2.0 M in THF	100-59-4	224448-100ML	714.87CNY	Detail
Aldrich	(224448) Phenylmagnesiumchloridesolution 2.0 M in THF	100-59-4	224448-800ML	2,597.40CNY	Detail

100-59-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name	Phenylmagnesium chloride

1.2 Other means of identification

Product number	-
Other names	Phenylmagnesium chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

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