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100-59-4

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100-59-4 Usage

Chemical Properties

yellowish-brown to dark brown solution

Uses

Different sources of media describe the Uses of 100-59-4 differently. You can refer to the following data:
1. In organic synthesis, especially in the production of hydrocarbons, alcohols, ketones, organic acids, amines, silicones, boranes.
2. Phenylmagnesium chloride (PhMgCl) solution is a common Grignard reagent used in the synthesis of (?)-phenserine and stephacidin B. It is employed in a variety of cross-coupling reactions. It can also be used as an electrolyte solution along with aluminium chloride (AlCl3) in the rechargeable magnesium batteries.
3. Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

General Description

This product has been enhanced for energy efficiency.

Check Digit Verification of cas no

The CAS Registry Mumber 100-59-4 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 0 respectively; the second part has 2 digits, 5 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 100-59:
(5*1)+(4*0)+(3*0)+(2*5)+(1*9)=24
24 % 10 = 4
So 100-59-4 is a valid CAS Registry Number.
InChI:InChI=1/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q-1;;+2/p-1

100-59-4 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • TCI America

  • (P1381)  Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L)  

  • 100-59-4

  • 250g

  • 640.00CNY

  • Detail
  • Alfa Aesar

  • (H51157)  Phenylmagnesium chloride, 1M in MeTHF   

  • 100-59-4

  • 100ml

  • 483.0CNY

  • Detail
  • Alfa Aesar

  • (H51157)  Phenylmagnesium chloride, 1M in MeTHF   

  • 100-59-4

  • 500ml

  • 1208.0CNY

  • Detail
  • Aldrich

  • (775045)  Phenylmagnesiumchloridesolution  1.0 M in 2-methyltetrahydrofuran

  • 100-59-4

  • 775045-100ML

  • 331.11CNY

  • Detail
  • Aldrich

  • (775045)  Phenylmagnesiumchloridesolution  1.0 M in 2-methyltetrahydrofuran

  • 100-59-4

  • 775045-4X25ML

  • 387.27CNY

  • Detail
  • Aldrich

  • (775045)  Phenylmagnesiumchloridesolution  1.0 M in 2-methyltetrahydrofuran

  • 100-59-4

  • 775045-800ML

  • 1,645.02CNY

  • Detail
  • Aldrich

  • (257125)  Phenylmagnesiumchloridesolution  2.0 M in THF

  • 100-59-4

  • 257125-200ML

  • 1,503.45CNY

  • Detail
  • Aldrich

  • (224448)  Phenylmagnesiumchloridesolution  2.0 M in THF

  • 100-59-4

  • 224448-100ML

  • 714.87CNY

  • Detail
  • Aldrich

  • (224448)  Phenylmagnesiumchloridesolution  2.0 M in THF

  • 100-59-4

  • 224448-800ML

  • 2,597.40CNY

  • Detail

100-59-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Phenylmagnesium chloride

1.2 Other means of identification

Product number -
Other names Phenylmagnesium chloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:100-59-4 SDS

100-59-4Relevant articles and documents

Disposable cartridge concept for the on-demand synthesis of turbo Grignards, Knochel–Hauser amides, and magnesium alkoxides

Adamo, Andrea,Berton, Mateo,McQuade, D. Tyler,Sheehan, Kevin

, p. 1343 - 1356 (2020)

Magnesium organometallic reagents occupy a central position in organic synthesis. The freshness of these compounds is the key for achieving a high conversion and reproducible results. Common methods for the synthesis of Grignard reagents from metallic magnesium present safety issues and exhibit a batch-to-batch variability. Tubular reactors of solid reagents combined with solution-phase reagents enable the continuous-flow preparation of organomagnesium reagents. The use of stratified packed-bed columns of magnesium metal and lithium chloride for the synthesis of highly concentrated turbo Grignards is reported. A low-cost pod-style synthesizer prototype, which incorporates single-use prepacked perfluorinated cartridges and bags of reagents for the automated on-demand lab-scale synthesis of carbon, nitrogen, and oxygen turbo magnesium bases is presented. This concept will provide access to fresh organomagnesium reagents on a discovery scale and will do so independent from the operator’s experience in flow and/or organometallic chemistry.

Movel photoacid generators, resist compositons, and patterning processes

-

Page/Page column 65, (2009/04/23)

Photoacid generators generate sulfonic acids of formula (1a) or (1c) upon exposure to high-energy radiation. ????????R1-COOCH(CF3)CF2SO3-H+?????(1a) ????????R1-O-COOCH(CF3)CF2SO3-H+?????(1c) R1 is a C20-C50 hydrocarbon group having a steroid structure. The photoacid generators are compatible with resins and can control acid diffusion and are thus suited for use in chemically amplified resist compositions.

Novel fluorohydroxyalkyl sulfonate salts and derivatives, photoacid generators, resist compositions, and patterning process

-

Page/Page column 29, (2010/11/27)

Sulfonate salts have the formula: CF3-CH(OH)-CF2SO3-M+ wherein M+ is a Li, Na, K, ammonium or tetramethylammonium ion. Because of inclusion within the molecule of a hydroxyl group which is a polar group, the sulfonic acids are effective for restraining the length of acid diffusion through hydrogen bond or the like. The photoacid generators that generate these sulfonic acids perform well during the device fabrication process including coating, pre-baking, exposure, post-exposure baking, and developing steps. The photoacid generators are little affected by water left on the wafer during the ArF immersion lithography.

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