1241374-72-0Relevant academic research and scientific papers
A Lewis acid-mediated conformational switch
Knipe, Peter C.,Lingard, Hannah,Jones, Ian M.,Thompson, Sam,Hamilton, Andrew D.
, p. 7937 - 7941 (2015/01/08)
Molecules that change conformation in response to a stimulus have numerous uses, such as artificial chemoreceptors, novel drug delivery strategies and liquid crystal technology. Here we describe the design, synthesis and conformational behaviour of an iso
PH-dependent conformational switching in 2,6-benzamidodiphenylacetylenes
Jones, Ian M.,Lingard, Hannah,Hamilton, Andrew D.
, p. 12569 - 12571 (2012/02/15)
The conformational equilibrium of a pH-dependent switch based on an intramolecularly H-bonded diphenylacetylene can be predictably biased by using electron-donating or -withdrawing groups (see scheme). Furthermore, protonation of the electron-donating dim
Designed molecular switches: Controlling the conformation of benzamido-diphenylacetylenes
Jones, Ian M.,Hamilton, Andrew D.
supporting information; experimental part, p. 3651 - 3653 (2010/10/03)
With the goal of creating a molecular switch, the hydrogen-bonded diphenylacetylene structure has been modified such that an equilibrium now exists between two intramolecular H-bonded states. Through X-ray crystallography and 1H NMR analysis it
