1241386-22-0Relevant academic research and scientific papers
Towards the synthesis of new dideoxy δ-dicarbonyl heptoses
Pistara, Venerando,Chiacchio, Maria Assunta,Corsaro, Antonino
experimental part, p. 1482 - 1485 (2010/10/02)
The preparation of a δ-dicarbonyl sugar thorough ring-opening, by a methoxymercuration-demercuration procedure, of a 5-spirocyclopropanated D-galactose derivative, is reported. This method constitutes a new route for the transformation of a hexose into new and interesting δ-dicarbonyl sugars, synthetic precursors of cyclitols, carba-and azasugars. Moreover this is, to our best knowledge, the first reported example of an elongation to a higher sugar starting from a spirocyclopropanated saccharide.
