124187-53-7Relevant academic research and scientific papers
STEREOSELECTIVE SYNTHESIS OF DI- AND TRISUBSTITUTED ALKENYLSTANNANES AND 2-(TRIMETHYLSTANNYL)-1,3-BUTADIENES. CONVERSION OF THE TRISUBSTITUTED ALKENYLSTANNANES TO THE TETRASUBSTITUTED ALKENES
Wang, Kung K.,Chu, Kai-Hsuan,Lin, Yuan,Chen, Jyun-Hung
, p. 1105 - 1118 (2007/10/02)
Di- and trisubstituted alkenylstannanes were synthesized by selective conversion of the dialkylboryl moiety of 3 to the alkenylcopper followed by treatment with methanol or alkyl halides.By starting from conjugated terminal enynes to produce 3, 2-(trimethylstannyl)-1,3-butadienes were similarly synthesized.The readily available trisubstituted alkenylstannanes are useful precursors for the synthesis of stereochemically defined tetrasubstituted alkenes.
