1241922-20-2Relevant academic research and scientific papers
Flexible gold-catalyzed regioselective oxidative difunctionalization of unactivated alkenes
De Haro, Teresa,Nevado, Cristina
supporting information; experimental part, p. 906 - 910 (2011/03/19)
AuI/AuIII catalytic cycles can trigger three highly regioselective alkene difunctionalization processes that involve the formation of C(sp3)iO, C(sp3)iN, and C(sp3)iC(sp 2) bonds. The react
Palladium-catalyzed alkoxyamination of alkenes with use of N -fluorobenzenesulfonimide as oxidant
Liskin, Dmitry V.,Sibbald, Paul A.,Rosewall, Carolyn F.,Michael, Forrest E.
supporting information; experimental part, p. 6294 - 6296 (2010/12/19)
Figure presented. A Pd-catalyzed alkoxyamination of protected aminoalkenes promoted by N-fluorobenzenesulfonimide is described. This mild transformation allows the direct formation of ethers from carbon-carbon double bonds. An unusual switch from exo to endo selectivity in polar solvents was discovered, allowing the selective formation of either regioisomer by careful choice of reaction conditions.
