1241922-22-4Relevant academic research and scientific papers
Palladium-catalyzed alkoxyamination of alkenes with use of N -fluorobenzenesulfonimide as oxidant
Liskin, Dmitry V.,Sibbald, Paul A.,Rosewall, Carolyn F.,Michael, Forrest E.
supporting information; experimental part, p. 6294 - 6296 (2010/12/19)
Figure presented. A Pd-catalyzed alkoxyamination of protected aminoalkenes promoted by N-fluorobenzenesulfonimide is described. This mild transformation allows the direct formation of ethers from carbon-carbon double bonds. An unusual switch from exo to endo selectivity in polar solvents was discovered, allowing the selective formation of either regioisomer by careful choice of reaction conditions.
