124193-22-2Relevant academic research and scientific papers
Rhenium-catalyzed reaction of carbonyl compounds with ketene silyl acetals
Nishiyama, Yutaka,Kaiba, Kenta,Umeda, Rui
, p. 793 - 795 (2010)
It was found that rhenium complex is an effective catalyst for the reaction of carbonyl compounds with ketene silyl acetals. A wide range of β-silyloxy esters is obtained by the treatment of carbonyl compounds with ketene silyl acetals in the presence of
New bis(imino)pyridine complexes of iron(II) and iron(III), and their catalytic-activity in the mukaiyama aldol reaction
Shejwalkar, Pushkar,Rath, Nigam P.,Bauer, Eike B.
, p. 57 - 66 (2014/01/06)
New iron(II) and iron(III) complexes bearing bis(imino)pyridine ligands were synthesized and successfully applied to the Mukaiyama aldol reaction. The two complexes [FeCl2 L] (L = bis(imino)pyridine ligand, 55% isolated yield) and [LFe(μCl)sub
New indenyl phosphinooxazoline complexes of iron and their catalytic activity in the Mukaiyama aldol reaction
Lenze, Matthew,Sedinkin, Sergey L.,Rath, Nigam P.,Bauer, Eike B.
supporting information; experimental part, p. 2855 - 2858 (2010/07/06)
New phosphinooxazoline (PHOX) η5-indenyl complexes of iron were synthesized and applied as catalysts in the Mukaiyama aldol reaction. Reaction of three different PHOX ligands with [Fe(η5-Ind)I(CO)2] afforded the iodide sal
Efficient Activation of Acetals, Aldehydes, and Imines toward Silylated Nucleophiles by the Combined Use of Catalytic Amounts of 2 and TMS-CN under Almost Neutral Conditions
Soga, Tsunehiko,Takenoshita, Haruhiro,Yamada, Masaaki,Mukaiyama, Teruaki
, p. 3122 - 3131 (2007/10/02)
In the presence of catalytic amount of a transition metal compound such as 2, Co(acac)2, or NiCl2, trimethylsilyl cyanide smoothly reacts with acetals to form α-methoxy carbonitriles in good yields.In the coexistence of catalytic amounts of Rh
Effective Activation of Carbonyl and Related Compounds with Phosphonium Salts. The Aldol and Michael Reactions of Carbonyl Compounds with Silyl Nucleophiles and Alkyl Enol Ethers
Mukaiyama, Teruaki,Matsui, Shigekazu,Kashiwagi, Kouichi
, p. 993 - 996 (2007/10/02)
In the presence of a catalytic amount of a phosphonium salt, aldol reaction of silyl enol ethers with aldehydes or acetals and the Michael reaction of silyl enol ethers with α,β-unsaturated ketones or acetals proceed smoothly to afford the corresponding a
