1241957-45-8Relevant articles and documents
4-iminocyclobutenones: Synthesis and building-blocks of aminohydroquinones and annulated quinolines
Oppermann, Gerrit,Stranberg, Michael,Moore, Harold W.,Schaumann, Ernst,Adiwidjaja, Gunadi
experimental part, p. 2027 - 2038 (2010/08/19)
Two methods are presented for the synthesis of the title compounds starting from cyclobutenediones: an alkoxide substitution approach and a Staudinger reaction. Unsaturated lithiumorganyls may be added to the remaining carbonyl group and on heating lead to ring enlargement in a cascading process. 4-Alkenyl or 4-aryl derivatives yield aminophenols or -naphthols; 4-alkynyl compounds give cyclopenta-annulated quinolines. Georg Thieme Verlag Stuttgart.