1242069-58-4Relevant academic research and scientific papers
2-(Chlorodiisopropylsilyl)-6-(trimethylsilyl)phenyl triflate: A modified platform for intramolecular benzyne cycloadditions
Takasu, Kiyosei,Takikawa, Hiroshi,Tawatari, Tsukasa
supporting information, p. 11863 - 11866 (2021/11/30)
2-(Chlorodiisopropylsilyl)-6-(trimethylsilyl)phenyl triflate serves as an efficient aryne precursor for intramolecular benzyne [4 + 2] or (2 + 2 + 2) cycloadditions. Key features of this precursor are (1) rapid connection of various arynophiles to the pre
An alkynylboronate cycloaddition strategy to functionalised benzyne derivatives
Kirkham, James D.,Delaney, Patrick M.,Ellames, George J.,Row, Eleanor C.,Harrity, Joseph P. A.
supporting information; experimental part, p. 5154 - 5156 (2010/10/19)
A new approach to benzyne precursors has been developed that involves the [4+2] cycloaddition of trimethylsilyl alkynylboronates with 2-pyrones, followed by oxidation and trifluoromethylsulfonylation of the boronate moiety. The Royal Society of Chemistry
