1242096-24-7Relevant academic research and scientific papers
Iron-catalyzed regio- and stereoselective addition of acid chlorides to alkynes
Wang, Bo,Wang, Shihua,Li, Pinhua,Wang, Lei
experimental part, p. 5891 - 5893 (2010/10/21)
An iron-catalyzed regio- and stereoselective addition of acid chlorides to alkynes has been described. The reaction utilizes an inexpensive iron catalyst system and it is suitable for the formation of a variety of bifunctional molecules. This is an inexpensive, regio-, stereoselective and atom-economical approach to β-chloro-α,β-unsaturated ketones from simple and readily available starting materials.
First sequential Mukaiyama-Michael reaction/crossed-Claisen condensation using two molar ketene silyl acetals and one molar α,β-unsaturated esters promoted by a NaOH catalyst
Tamagaki, Hiroaki,Nawate, Yuuya,Nagase, Ryohei,Tanabe, Yoo
supporting information; experimental part, p. 5930 - 5932 (2010/10/21)
The NaOH-catalyzed first sequential Mukaiyama-Michael reaction/crossed- Claisen condensation is developed using two molar ketene silyl acetals and one molar α,β-unsaturated esters in either a stepwise or one-pot manner.
