124222-36-2Relevant academic research and scientific papers
Radical-Type Cyclisation of Dienes, III. - Radical-Type Cyclisation of (R)-(-)-Carvone - On the Influence of Charge-Transfer Interactions on the Optical Rotation
Weinges, Klaus,Maurer, Wolfgang,Reichert, Hans,Schilling, Gerhard,Oeser, Thomas,Irngartinger, Hermann
, p. 901 - 905 (2007/10/02)
Under the conditions of radical cyclisation, a 1:1 diastereomeric mixture of (1R,2S,5R,6R)-(+)- (2a) and (1R,2S,5R,6S)-(+)-6-methoxy-2,6-dimethylbicyclooctan-3-ones (2b) is obtained from (R)-(-)-carvone in 70percent yield.The configurations of 2a a
