124242-38-2Relevant academic research and scientific papers
RADICAL C-Se BOND CLEVAVAGE OF SELENONIUM SALTS WITH GRIGNARD REAGENTS OR MAGNESIUM METAL
Hori, Mikio,Kataoka, Tadashi,Shimizu, Hiroshi,Tsutsumi, Kazuhiro
, p. 981 - 984 (2007/10/02)
The reaction of 2-methylisoselenochromanium salt with Grignard reagents afforded the reductive ring-opened product by the single electron transfer (SET) mechanizm, not by the self-decomposition of ?-selenurane.The same reduction was observed in the reaction of the selenonium salt with magnesium metal.Some other selenonium salts were easily reduced by magnesium metal to give ring-opened products.
