124263-12-3

Upstream product

• 104640-83-7 (3aR,7aR)-(+)-tetrahydroactinidiolide 
• 90987-31-8 (+/-)-1-(3-furyl)-(2α-hydroxy-2,6,6-trimethylcyclohexyl)ethanone 
• 69924-94-3 (+/-)-(R^*R^*)-α-<(2,2-dimethyl-6-methylenecyclohexyl)methyl>furan-3-methanol 
• 69924-96-5 (+/-)-(αRS,3'RS,4'SR)-α-(3-furyl)-5,5-dimethyl-1-oxaspiro<2.5>octane-4-ethanol 
• 69924-96-5 (+/-)-(αRS,3'SR,4'RS)-α-(3-furyl)-5,5-dimethyl-1-oxaspiro<2.5>octane-4-ethanol 
• 124263-09-8 (1'R,2'R)-1-(3-furyl)-2-(2'-hydroxy-2',6',6'-trimethylcyclohexyl)-1-ethanone 
• 124263-08-7 (1'S,2'S)-1-(3-furyl)-2-(2'-hydroxy-2',6',6'-trimethylcyclohexyl)-1-ethanone 
• 105426-84-4 2-(5',5'-dimethyl-1'-oxaspiro<2.5>octan-4'-yl)-1-(3-furyl)ethanone 
• 105426-83-3 2-(2',2'-dimethyl-6'-methylenecyclohexyl)1-(3-furyl)ethanone 
• 547-15-9 2-(6',6'-Dimethyl-2'-methylenecyclohexyl)ethanal 
• 76337-19-4 (3,3-Dimethylcyclohexenyl)methyl vinyl ether 
• 69924-97-6 (+/-)-(1'SR,2'SR)-α-<(2'-hydroxy-2',6',6'-trimethylcyclohexyl)methyl>furan-3-methanol 
• 37531-07-0 (+/-)-(3aα,7aβ)-4,4-7a-trimethyl-3a,4,5,6,7,7a-hexahydrobenzofuran-2(3H)-one 
• 53101-93-2 3-furyllithium 

Downstream Products

• 90987-31-8 (+/-)-1-(3-furyl)-(2α-hydroxy-2,6,6-trimethylcyclohexyl)ethanone 
• 69924-97-6 (+/-)-(αRS,1'SR,2'SR)-α-<(2'-hydroxy-2',6',6'-trimethylcyclohexyl)methyl>furan-3-methanol 
• 69924-97-6 (+/-)-(αRS,1'RS,2'RS)-α-<(2'-hydroxy-2',6',6'-trimethylcyclohexyl)methyl>furan-3-methanol 

Relevant academic research and scientific papers

Synthesis of Mono- and Sesquiterpenoids, XIX Synthesis of the Enantiomers of Ancistrofuran, a Defensive Compound from Ancistrotermes cavithorax

The synthesis of the enantiomers (1 and 1') of ancistrofuran was achieved starting from (S)-3-hydroxy-2,2-dimethylcyclohexanone.

Stereoselective Synthesis of (+/-)-Ancistrofuran and its Stereoisomers

The four possible stereoisomers of ancistrofuran have been prepared from γ-cyclohomocitral.Addition of 3-furyl-lithium yielded two epimeric alcohols.Each alcohol was epoxidised with m-chloroperbenzoic acid and reduction with lithium aluminium hydride gave

Stereoselective Synthesis of (+/-)-Ancistrofuran: Stereoselective Reduction of a γ-Hydroxyketone

A remarkably stereoselective reduction of a γ-hydroxyketone with two equiv. of lithium triethylborohydride has been observed and this effect has been suggested to originate from 'chelation control'; the reaction has been utilised in a short stereoselectiv