124300-58-9

Basic information

• Product Name: Benzaldehyde, 2-(1,3-butadienyl)-, (Z)- (9CI)
• Synonyms: Benzaldehyde, 2-(1,3-butadienyl)-, (Z)- (9CI)
• CAS NO: 124300-58-9
• Molecular Formula: C11H10O
• Molecular Weight: 158.1965
• Product Categories: ALDEHYDE
• Mol File: 124300-58-9.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzaldehyde, 2-(1,3-butadienyl)-, (Z)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzaldehyde, 2-(1,3-butadienyl)-, (Z)- (9CI)(124300-58-9)
• EPA Substance Registry System: Benzaldehyde, 2-(1,3-butadienyl)-, (Z)- (9CI)(124300-58-9)

Safety Data

• Hazardous Substances Data: 124300-58-9(Hazardous Substances Data)

Upstream product

• 6630-33-7 ortho-bromobenzaldehyde 
• 125643-35-8 1-bromo-2-(buta-1,3-dien-1-yl)benzene 
• 68-12-2 N,N-dimethyl-formamide 
• 125643-35-8 (E)-1-bromo-2-(buta-1,3-dienyl)benzene 
• 591-50-4 iodobenzene 

Relevant articles and documents

Highly regioselective and diastereodivergent aminomethylative annulation of dienyl alcohols enabled by a hydrogen-bonding assisting effect

A ligand-controlled palladium-catalyzed highly regioselective and diastereodivergent aminomethylative annulation of dienyl alcohols with aminals has been established, which allows for producing either cis- or trans-disubstituted isochromans in good yields with complete regioselectivity and good to excellent diastereoselectivity. Moreover, the chiral cis-products were also obtained in good yields with up to 94% ee by using a chiral phosphinamide as the ligand. Mechanistic studies revealed that the hydroxyl group plays a key role in facilitating the Pd-catalyzed Heck insertion regioselectively taking place across the internal CC bond of conjugated dienes. This journal is

Ruthenium-catalyzed transformation of 3-benzyl but-1-ynyl ethers into 1,3-dienes and benzaldehyde via transfer hydrogen

TpRuPPh3(CH3CN)2PF6 catalyzed the transformation of various 3-benzyl but-1-ynyl ethers into dienes and benzaldehyde at a catalyst loading of 5 mol %. This process represents an atypical pattern of transfer hydrogenation. This catalytic reaction can be applied to various derivatives of 2-ethynyl tetrahydrofurans and pyrans to cleave their ether rings and gives diene and tethered aldehyde functionalities, respectively.

Intramolecular reactions of α-azidocinnamates with 4-substituted 1,3-dienes

The synthesis of new 8,9-benzo-6-aza-bicyclo[3.2.2]nona-3.6.8-trienes 14 by intramolecular reaction of α-azidocinnamates 9 with alkyl- and phenylsubstituted ortho-butadienyl side chains is reported, as is the formation of the new 1-aza-2-carbomethoxy-7,8-benzo-tricyclo[4.30.02,9]nona-4,7-diene 15.