124318-69-0

Basic information

• Product Name: 1,10-Phenanthroline, 2,9-bis(2,6-dimethoxyphenyl)-
• CAS NO: 124318-69-0
• Molecular Formula: C28H24N2O4
• Molecular Weight: 452.51
• Mol File: 124318-69-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 1,10-Phenanthroline, 2,9-bis(2,6-dimethoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,10-Phenanthroline, 2,9-bis(2,6-dimethoxyphenyl)-(124318-69-0)
• EPA Substance Registry System: 1,10-Phenanthroline, 2,9-bis(2,6-dimethoxyphenyl)-(124318-69-0)

Safety Data

• Hazardous Substances Data: 124318-69-0(Hazardous Substances Data)

Upstream product

• 39588-59-5 3,6,7,9-tetrahydro-5H-<1,4>diazepino<1,2,3,4-lmn><1,10>phenanthroline-3,9-dione 
• 15302-99-5 6,7-dihydro-5H-[1,4]diazepino[1,2,3,4-l,m,n][1,10]phenanthroline-4,8-diium dibromide 
• 16932-45-9 1-bromo-2,6-dimethoxybenzene 
• 66-71-7 1,10-Phenanthroline 
• 250665-25-9 C₁₀H₁₅BO₄ 
• 151-10-0 1,3-Dimethoxybenzene 
• 23112-96-1 (2,6-dimethoxyphenyl)boronic acid 
• 29176-55-4 2,9-dichloro-[1,10]phenanthroline 

Downstream Products

• 356791-71-4 2,9-bis[2,6-bis(pent-4-enoxy)phenyl]-1,10-phenanthroline 
• 356791-73-6 2,9-bis[2,6-bis(hex-5-enoxy)phenyl]-1,10-phenanthroline 
• 192226-51-0 C₃₂N₂O₇H₃₀Cu(CH₃O)2C₆H₃C₁₂N₂H₆C₆H₃(OCH₃)2⁽¹⁺⁾ 
• 445460-96-8 [(CH₃O)2C₆H₃C₁₂N₂H₆C₆H₃(OCH₃)2]2Cu⁽¹⁺⁾ 
• 878269-60-4 (2,9-dimesityl-1,10-phenanthroline)(1,10-phenanthroline)copper(I) 
• 1196061-70-7 Zn(C₁₂H₆N₂(C₆H₃(OCH₃)2)2)(C₅H₃N(C₅H₄N)2)⁽²⁺⁾ 
• 1196061-73-0 Cu(C₁₂H₆N₂(C₆H₃(OCH₃)2)2)(C₁₂H₈N₂)⁽¹⁺⁾*PF₆^(1-)=CuC₄₀H₃₂N₄O₄PF₆ 
• 201403-31-8 Cu(CH₃OC₆H₄C₁₂H₆N₂C₅H₃NCH₃)2⁽¹⁺⁾*PF₆^(1-)=[Cu(CH₃OC₆H₄C₁₂H₆N₂C₅H₃NCH₃)2]PF₆ 

Relevant articles and documents

Towards allosteric receptors synthesis of β-cyclodextrin- functionalised 2,2'-bipyridines and their metal complexes

Herein, we present three new 2,2'-bipyridines that carry two β-cyclodextrin moieties in different substitution patterns. When coordinated by zinc(II) or copper(I) ions (or their complexes), these compounds undergo conformational changes and switch between

A facile route to Aryl-substituted 1,10-phenanthrolines by means of Suzuki coupling reactions between substituted areneboronic acids and halogeno-1,10-phenanthrolines

Twelve new mono- or diaryl-substituted 1,10-phenanthrolines (17 and 18) have been synthesized. The key step is a Suzuki coupling reaction between the substituted areneboronic acids 6, 11, and 15 and the mono- and dihalo-1,10-phenanthrolines 16. The syntheses of bis-ortho-substituted boronic acids 6, 11, and 15 from substituted arenes 5 or substituted bromoarenes 10 and 14 by lithiation and subsequent treatment with trimethyl borate is described. Not only 2,9-diiodo- (16c) but also 2,9-dichloro-1,10-phenanthroline (16b) can be used with good yields (65-92%) in the described Suzuki coupling. For the syntheses of unsymmetrically substituted 1,10-phenanthrolines 18b, 18i, and 18j, the use of 2- chloro-9-iodo-1,10-phenanthroline is not necessary; two different bis-ortho-substituted arene rings can be introduced stepwise in 46 to 64% total yield. ( Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002).