124477-06-1

Basic information

• Product Name: 2,6-di-O-benzoyl-3,4-O-isopropylidene-β-D-galactopyranosyl phenyl sulphone
• Synonyms: 2,6-di-O-benzoyl-3,4-O-isopropylidene-β-D-galactopyranosyl phenyl sulphone
• CAS NO: 124477-06-1
• Molecular Weight: 552.602
• Mol File: 124477-06-1.mol

Chemical Properties

• CAS DataBase Reference: 2,6-di-O-benzoyl-3,4-O-isopropylidene-β-D-galactopyranosyl phenyl sulphone(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6-di-O-benzoyl-3,4-O-isopropylidene-β-D-galactopyranosyl phenyl sulphone(124477-06-1)
• EPA Substance Registry System: 2,6-di-O-benzoyl-3,4-O-isopropylidene-β-D-galactopyranosyl phenyl sulphone(124477-06-1)

Safety Data

• Hazardous Substances Data: 124477-06-1(Hazardous Substances Data)

Upstream product

• 270075-72-4 phenyl 1-thio-3,4-O-isopropylidene-6-O-(1-methoxyl-1-methylethyl)-β-D-galactopyranoside 
• 124476-99-9 phenyl 2,6-di-O-acetyl-3,4-O-isopropylidene-1-thio-β-D-galactopyranoside 
• 120095-47-8 phenyl 3,4-O-isopropylidene-1-thio-β-D-galactopyranoside 
• 98-88-4 benzoyl chloride 
• 2936-70-1 (2R,3S,4S,5R,6S)-2-Hydroxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3,4,5-triol 
• 124477-00-5 phenyl 2,6-di-O-benzoyl-3,4-O-(isopropylidene)-1-thio-β-D-galactopyranoside 

Downstream Products

• 124477-12-9 2,6-anhydro-5-deoxy-3,4-O-isopropylidene-D-arabino-hex-5-enitol 

Relevant articles and documents

PREPARATION OF PYRANOID GLYCAL DERIVATIVES FROM PHENYL THIOGLYCOSIDES AND GLYCOSYL PHENYL SULPHONES

Phenyl thioglycopyranosides with various protecting groups (acetal, ether, ester) underwent reductive lithiation at C-1, followed by rapid elimination of the 2-substituent, when treated with lithium naphthalenide in tetrahydrofuran at low temperature.Thus

CONVENIENT SYNTHESES OF SUBSTITUTED PYRANOID GLYCALS FROM THIOPHENYL GLYCOSIDES AND GLYCOSYL PHENYLSULFONES

A series of substituted thiophenyl glycosides and glycosyl phenylsulfones were converted in high yield into glycals after reductive lithiation with lithium naphthalenide, followed by elimination of the substituent at C-2.