1244778-22-0

Basic information

• Product Name: [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-(trimethylsilylethynyl)phenylethynyl]porphynato]nickel(II)
• Synonyms: [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-(trimethylsilylethynyl)phenylethynyl]porphynato]nickel(II)
• CAS NO: 1244778-22-0
• Molecular Weight: 1016.08
• Mol File: 1244778-22-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-(trimethylsilylethynyl)phenylethynyl]porphynato]nickel(II)(CAS DataBase Reference)
• NIST Chemistry Reference: [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-(trimethylsilylethynyl)phenylethynyl]porphynato]nickel(II)(1244778-22-0)
• EPA Substance Registry System: [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-(trimethylsilylethynyl)phenylethynyl]porphynato]nickel(II)(1244778-22-0)

Safety Data

• Hazardous Substances Data: 1244778-22-0(Hazardous Substances Data)

Upstream product

• 952190-21-5 [Ni((3,5-di-tert-butylphenyl)2(Ph)(HCC)C₂₀H₈N₄)] 
• 16116-78-2 (4-bromophenyl)(trimethylsilyl)acetylene 

Downstream Products

• 1309441-76-6 [5,15-bis(3,5-di-tert-butylphenyl)-10-phenyl-20-[p-ethynylphenylethynyl]porphynato]nickel(II) 

Relevant articles and documents

Extending conjugation in porphyrin dimer carbocations

The addition of alkynyl porphyrins to carbonyl compounds was used to prepare a series of porphyrin dimer tertiary alcohols. Treatment of these alcohols with acid gave conjugated carbocations with three to nine carbon atoms bridging between the porphyrins. All these carbocations show strong absorption in the near-IR region between 1000-1800 nm. The absorption spectra exhibit a length-dependence similar to that of polymethine cyanines, with a bathochromic shift of approximately 200 nm (900 cm-1) per alkyne. The longest of these chromophores has an absorption maximum at 1623 nm (in CHCl3 with 2% trifluoroacetic acid). The symmetry of the π-system has a strong effect on the position, intensity and width of the absorption bands. The stability of the cations in solution decreases with increasing bridge length. The Royal Society of Chemistry 2010.