1245321-65-6Relevant academic research and scientific papers
Gold-catalyzed stereoselective synthesis of 9-oxabicyclo[3.3.1]nona-4,7- dienes from diverse 1-oxo-4-oxy-5-ynes: A viable formal [4 + 2] cycloaddition on an s-trans-heterodiene framework
Teng, Tse-Min,Das, Arindam,Huple, Deepak B.,Liu, Rai-Shung
, p. 12565 - 12567 (2010)
We report a highly stereoselective Au-catalyzed synthesis of 9-oxabicyclo[3.3.1]nona-4,7-dienes from diverse 1-oxo-4-oxy-5-ynes. Formation of these highly strained anti-Bredt oxacycles implies the workability of an unprecedented 1,4-dipole of s-trans-meth
