124539-39-5Relevant articles and documents
The Reaction of Cobalt(III) Porphyrins with α-Diazo-β-Dicarbonyl Compounds
Setsune, Jun-ichiro,Iida, Toshiya,Kitao, Teijiro
, p. 885 - 888 (2007/10/02)
Cobalt(III) porphyrins reacted with α-diazo-β-dicarbonyl compounds to give N,Co-methano bridged Co(III) porphyrins in good yields.The axial ligand and the peripheral substituents have great influence on the insertion of the carbenes and on the subsequent transformation to Co(III) N-alkylporphyrins with a linkage.