60166-11-2Relevant articles and documents
Influence of the Coordination Surrounding of Co(II)- and Co(III)-Tetraphenylporphyrins on Their Destruction Processes in the Presence of Organic Peroxides
Mamardashvili,Simonova,Chizhova,Mamardashvili, N. Zh.
, (2018)
The interaction of Co(II)- and Co(III)-5,10,15,20-tetraphenylporphyrins with tert-butylhydroxyperoxide and di-tert-butylhydroxyperoxide in benzene at 298 K were studied by spectrophotometry and 1H NMR spectroscopy. Kinetic parameters of the des
Synthesis of novel cobalt(III) porphyrin-phosphoryl complexes
Tse, Andy K.-S.,Mak, Kin Wah,Chan, Kin Shing
, p. 2651 - 2655 (2008/10/08)
Novel porphyrinato[phosphoryl] cobalt(III) complexes were synthesized unexpectedly through the reaction of BrCoIII(por) (por = porphyrinato dianion) with Me3SiLi (MeLi-Me6Si2-HMPA) and MeLi in HMPA at 78 °C. Phosphoryl complexes were also synthesized from HMPA-K and the appropriate organophosphoryl chloride-K As a result, Me3SiLi may not always be an appropriate silylating agent for bulky organometallic electrophiles.