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2,2',6,6'-TETRAKIS(METHOXYCARBONYL)-4,4'-BIPYRIDINE, also known as TMCBP, is a chemical compound with a molecular formula C28H24N2O8. It is a highly symmetrical, tetra-substituted bipyridine derivative that is widely used in coordination chemistry and material science. TMCBP has a unique structure with four methoxycarbonyl groups attached to the four nitrogen atoms of the bipyridine core, which makes it a versatile ligand for various metal ions.

124558-62-9

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124558-62-9 Usage

Uses

Used in Coordination Chemistry:
2,2',6,6'-TETRAKIS(METHOXYCARBONYL)-4,4'-BIPYRIDINE is used as a versatile ligand for [forming strong coordination bonds with metal ions] due to [its unique structure with four methoxycarbonyl groups attached to the bipyridine core].
Used in Material Science:
2,2',6,6'-TETRAKIS(METHOXYCARBONYL)-4,4'-BIPYRIDINE is used as a component in [designing metal-organic frameworks (MOFs) and coordination polymers] for [its ability to form strong coordination bonds with metal ions].
Used in Catalysis:
2,2',6,6'-TETRAKIS(METHOXYCARBONYL)-4,4'-BIPYRIDINE is used as a catalyst or catalyst precursor in [various catalytic processes] because of [its interesting photophysical and electrochemical properties].
Used in Sensors:
2,2',6,6'-TETRAKIS(METHOXYCARBONYL)-4,4'-BIPYRIDINE is used as a sensing material in [developing sensors] for [its unique photophysical and electrochemical properties].
Used in Optoelectronic Devices:
2,2',6,6'-TETRAKIS(METHOXYCARBONYL)-4,4'-BIPYRIDINE is used as a component in [optoelectronic devices] for [its interesting photophysical properties].

Check Digit Verification of cas no

The CAS Registry Mumber 124558-62-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,4,5,5 and 8 respectively; the second part has 2 digits, 6 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 124558-62:
(8*1)+(7*2)+(6*4)+(5*5)+(4*5)+(3*8)+(2*6)+(1*2)=129
129 % 10 = 9
So 124558-62-9 is a valid CAS Registry Number.

124558-62-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name dimethyl 4-[2,6-bis(methoxycarbonyl)pyridin-4-yl]pyridine-2,6-dicarboxylate

1.2 Other means of identification

Product number -
Other names TETRAMETHYL 4,4'-BIPYRIDINE-2,2',6,6'-TETRACARBOXYLATE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:124558-62-9 SDS

124558-62-9Downstream Products

124558-62-9Relevant academic research and scientific papers

A Highly Stable Organic Radical Cation

Berville, Mathilde,Richard, Jimmy,Stolar, Monika,Choua, Sylvie,Le Breton, Nolwenn,Gourlaouen, Christophe,Boudon, Corinne,Ruhlmann, Laurent,Baumgartner, Thomas,Wytko, Jennifer A.,Weiss, Jean

, p. 8004 - 8008 (2018)

Functionalization of a methylviologen with four methyl ester substituents significantly facilitates the first two reduction steps. The easily generated radical cation shows markedly improved air stability compared to the parent methylviologen, making this derivative of interest in organic electronic applications.

Rigid and Compact Binuclear Bis-hydrated Gd-complexes as High Relaxivity MRI Agents

Leone, Loredana,Guarnieri, Luca,Martinelli, Jonathan,Sisti, Massimo,Penoni, Andrea,Botta, Mauro,Tei, Lorenzo

, p. 11811 - 11817 (2021/07/09)

The first binuclear Gd-complex of the 12-membered pyridine-based polyaminocarboxylate macrocyclic ligand PCTA was synthesized by C?C connection of the pyridine units through two different synthetic procedures. A dimeric AAZTA-ligand was also synthesized w

A Convenient Synthesis of 2,2',6,6'-Tetramethyl-4,4'-bipyridine and Its Oxidation to 2,2',6,6'-Tetracarboxy-4,4'-bipyridine

Huenig, Siegfried,Wehner, Ingeborg

, p. 552 - 554 (2007/10/02)

By reaction of 2,6-dimethylpyridine (1b) with sodium the tetrahydro-4,4'-bipyridine bis-sodium salt 2b is formed.Of different dehydrogenation reagents tested, only sulfur dioxide affords the title compound 3b, in 49percent overall yield.By oxidation of 3b with chromium trioxide, 2,2',6,6'-tetracarboxy-4,4'-bipyridine (3c, 70percent) is produced, a valuable precursor for several 2,2',6,6'-tetrasubstituted 4,4'-bipyridines, e.g., the corresponding acid chloride 3d and the carboxylic esters 3e and 3f.

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