1245616-70-9

Basic information

• Product Name: N-[(3,3-dimethylcycloprop-1-enyl)phenylmethyl]-4-methylbenzenesulfonamide
• Synonyms: N-[(3,3-dimethylcycloprop-1-enyl)phenylmethyl]-4-methylbenzenesulfonamide
• CAS NO: 1245616-70-9
• Molecular Weight: 327.447
• Mol File: 1245616-70-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-[(3,3-dimethylcycloprop-1-enyl)phenylmethyl]-4-methylbenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(3,3-dimethylcycloprop-1-enyl)phenylmethyl]-4-methylbenzenesulfonamide(1245616-70-9)
• EPA Substance Registry System: N-[(3,3-dimethylcycloprop-1-enyl)phenylmethyl]-4-methylbenzenesulfonamide(1245616-70-9)

Safety Data

• Hazardous Substances Data: 1245616-70-9(Hazardous Substances Data)

Upstream product

• 51608-60-7 N-(benzylidene)-p-methylbenzenesulfonamide 
• 23534-97-6 1,1,3‐tribromo‐2,2‐dimethylcyclopropane 

Downstream Products

• 1245616-53-8 N-[(3,3-dimethylcycloprop-1-enyl)phenylmethyl]-4-methyl-N-(2-methylallyl)benzenesulfonamide 
• 1245616-52-7 N-allyl-N-[(3,3-dimethylcycloprop-1-enyl)phenylmethyl]-4-methylbenzenesulfonamide 

Relevant articles and documents

Gold(I)-catalysed cycloisomerisation of 1,6-cyclopropene-enes

The gold(I)-catalysed cycloisomerisation of appropriately substituted 1,6-cyclopropene-enes proceeds through regioselective electrophilic ring opening of the three-membered ring to generate an alkenyl gold carbenoid that achieves the intramolecular cyclopropanation of the remote olefin. This strategy allows straightforward, highly efficient and diastereoselective access to a variety of substituted 3-oxaand 3-azabicycloachtungtrenung[4.1.0]heptanes, as well as to bicycloachtungtrenung[4.1.0]heptan-3-ol derivatives. Since the isopropylidene group in the resulting cycloisomerisation products can be subjected to ozonolysis, 3,3-dimethylcyclopropenes behave as interesting surrogates for a-diazoketones.