1245643-36-0Relevant academic research and scientific papers
Silver-Mediated C–H Difluoromethylation of Arenes
Li, Jialiang,Wan, Wen,Ma, Guobin,Chen, Yunrong,Hu, Qingyang,Kang, Kai,Jiang, Haizhen,Hao, Jian
supporting information, p. 4916 - 4921 (2016/10/13)
The first AgI-mediated C–H ethoxycarbonyl difluoromethylation with TMSCF2COOEt (TMS = trimethylsilyl) has been developed. The radical difluoromethylation proceeds smoothly to give the difluoromethylated arenes in moderate to high yie
Manufacturing method of making heteroarylacetic compd. defluoromethyl
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Paragraph 0129-0131, (2018/10/03)
PROBLEM TO BE SOLVED: To provide a method for easily producing a difluoromethyl heteroaryl compound with high yield at low cost. SOLUTION: In the method for producing the difluoro methyl heteroaryl compound, a halogenated heteroaryl compound and a α-silyldifluoro acetate ester compound are reacted with each other in the presence of a metal halogenated compound. COPYRIGHT: (C)2012,JPOandINPIT
