124573-73-5Relevant academic research and scientific papers
Cyano-borrowing: Titanium-catalyzed direct amination of cyanohydrins with amines and enantioselective examples
Li, Qian,Li, Qing-Hua,Li, Wan-Fang,Li, Zhao-Feng,Liu, Tang-Lin,Peng, Yun-Gui,Ren, Li-Qing,Tao, Jing
supporting information, p. 651 - 654 (2020/01/28)
The direct amination of cyanohydrins with amines via a catalytic cyano-borrowing reaction was developed. The transformation features broad substrate scope, excellent functional group compatibility, and very mild and simple operations. Moreover, a titanium
Vanadium-catalyzed oxidative Strecker reaction: α-C-H cyanation of para-methoxyphenyl (PMP)-protected primary amines
Chen, Chuo,Zhu, Chen,Xia, Ji-Bao
supporting information, p. 232 - 234 (2014/01/06)
We describe an oxidative Strecker reaction that allows for direct cyanation of para-methoxyphenyl (PMP)-protected primary amines. A vanadium(V) complex was used as the catalyst and TBHP as the oxidant. The cyanation occurs at the α-C position bearing either an alkyl or an aromatic group. This method provides a direct access to α-aminonitrile from amines with one-carbon extension.
Synthesis of Some New 3,4-Diarylsydnones
Csongar, Ch.,Mueller, I.,Slezak, H.,Klebsch, H.-J.,Tomaschewski, G.
, p. 1006 - 1014 (2007/10/02)
The synthesis of some new sydnones 4 is described.Their characteristic absorption maxima, mass spectroscopic fragmentation and C=O-valence vibrations are given.The sydnones 4 are synthezid by nitrosation of C,N-diarylglycines 3 (from strecker synthesis) a
